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Polymer Cased Ammo (PCA Spectrum) by NATEC was introduced in the mid 2000's and was offered primarily in 5.56x45 though other calibers were in the works. It featured a polymer case with a brass rim. It was tested in an article in Small Arms Review Magazine (link following) in 2006.
If you would like more extensive testing of this new. old stock I have around, please let me know in the comments and I'll be happy to accommodate as many requests as I can.
Firearm is a BCI Defense Pistol with SB Tactical collapsible Brace. Optic is Trijicon Reflex from Optics Planet. Suppressor is a Gemtech TREK-T Titanium 5.56 suppressor.
GhostKnife information available at www.Bigshooterist.com
Thermal Imagers (SeeK and Flir) available at OpticsPlanet.
Direct Link to original article in Small Arms Review Magazine. http://www.smallarmsreview.com/display.article.cfm?idarticles=144